a new facile route to synthesize thieno[3,2-e][1,2,4]triazolo[4,3-c]pyrimidine derivatives

نویسندگان

mehdi soleimany

jalil lari

hooshang vahedi

morteza imanpour

چکیده

a new facile route for synthesis of 3- (aryl) -8, 9- di (alkyl) thieno [3,2-e] [1,2,4] triazolo pyrimidines derivative from the same starting material, 2- amino - 4,5 -di (alkyl) thiophene-3- carboxamide, has been developed through heterocyclization of the corresponding arylidene-hydrazino -5,6 -di (alkyl) thieno [2,3-d] pyrimidine under refluxing condition with acetic anhydride followed by air oxidation. the products were obtained in high yield with an easy work-up in simple reaction along with the purification of products by non-chromatographic method. this general synthetic procedure can be extended to the preparation of a wide variety of isomeric triazoles using 2-amino thiophene-3-carboxamide bifunctional derivatives.

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عنوان ژورنال:
iranian chemical communication

ناشر: payame noor university (pnu)

ISSN 2423-4958

دوره 3

شماره Issue 2, pp. 85-179 2015

کلمات کلیدی
[ ' t h i e n o [ 3 ' , 2 , ' e ] [ 1 ' , 2 , ' 4 ] t r i a z o l o [ 4 ' , 3 , ' c ] p y r i m i d i n e s h e t e r o c y c l i z a t i o n a c e t i c a n h y d r i d e a i r o x i d a t i o n ' ]

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